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Alternatives to ODS

Ozone depleting substances (ODS) have become widely used in our society, but we are not dependent on them. With the exception of a few small applications that are considered essential, such as the use of ozone-depleting substances in Meter dose inhalers (MDIs) for delivering asthma medication, there is a wide range of alternatives.

Refrigerants

Options for alternatives in refrigeration will depend on the size and type of system. It will also depend on the application as ozone depleting substances have been used as both the refrigerant gases and the propellant in the foam-blowing process. Replacements with lower ozone depleting potentials - such as HCFCs - or no ozone depleting potential - such as HFCs, hydrocarbons and ammonia - are now available to reduce the potential impact of new machinery on the ozone layer. In some cases, through the use of alternative technologies, it might be possible to minimise or even eliminate the use of refrigerants altogether. Previously, measures for reducing the ozone depleting impact of refrigeration included, where possible, the recovery, recycling and destruction of the refrigerant gas.

Foams

HCFCs were an important transitional substance in the phase out of CFCs for foam blowing. Although still ozone depleting, HCFCs have a much lower ozone depleting potential that the CFCs previously used in this application. However, with the advance of technology, the transfer from HCFCs to completely non-ozone depleting substances such as HFCs and pentane has almost been finalised at the time of writing. EC Regulation 2037/2000 prohibits the use of HCFCs in the production of all foams from 1 January 2004. Further information can be found in the Department of Trade and Industry/Department for Environment, Food and Rural Affairs (formerly DETR) booklet 'Guidance on the new EC Regulation No 2037/2000 on substances that deplete the ozone layer'.

Solvents

The use of solvents containing CFCs, 1,1,1-trichloroethane, bromochloromethane and carbon tetrachloride has been prohibited under EC Regulation 2037/2000. These substances were used in a variety of applications such as in the cleaning of metal and precision-engineered parts as well as in dry cleaning processes. Dependency on solvents for cleaning applications can be greatly reduced by minimising contamination in the first place. Eliminating the need for the substances would reduce the cost of meeting emission controls, cut recycling costs and reduce waste disposal costs. Further information can be found in the Department of Trade and Industry/Department for Environment, Food and Rural Affairs (formerly DETR) booklet 'Phase out of Ozone Depleting Solvents'.

Fire fighting

Halon use in both fixed and portable systems became widespread due to its exceptional fire extinguishing and explosion suppression properties. Although halons represent less than 2% by weight of the historic production of CFCs, they are considered to be responsible for up to 25% of ozone layer depletion. It is because of this that the EU decided to incorporate a total decommissioning of all non-critical halon systems into EC Regulation 2037/2000. From December 2002, the sale and use of halons, including recycled and reclaimed material was prohibited. Total decommissioning of non-critical systems must be achieved by 31 December 2003. Water mist or detection-only devices can replace many systems, however, as the severity and type of hazards differ it is best to obtain the advice of a technical expert before replacing any system. Further information can be found in the Department of Trade and Industry/Department for Environment, Food and Rural Affairs (formerly DETR) booklet 'Phase out of Halons'.

Methyl Bromide

Methyl bromide which is both toxic and ozone depleting, is a substance used in fumigation and soil sterilisation. Although no direct replacement exists there are a number of alternatives or potential alternatives available that can be used, either alone or in combination, as the situation requires.



Methyl bromide will be phased-out in developed countries in 2005, although some critical use exemptions may be agreed by UNEP. Further information can be found in the Department of Trade and Industry/Department for Environment, Food and Rural Affairs (formerly DETR) booklet 'Ban on Methyl Bromide'.





© Crown, The Ozone Layer, Defra (2003)

Page updated: Friday, September 14, 2007